Kinetics and mechanism of hydrolysis of benzimidazolylcarbamates

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Kinetics and Mechanism of Hydrolysis of Benzimidazolylcarbamates

Através da carbamoilação do 2-aminobenzimidazole com diferentes cloroformatos substituídos, sintetizaram-se novos N-[1-(2-amino)benzimidazolil]carbamatos. Estudouse a hidrólise em meio aquoso destes carbamatos numa gama de pH compreendida entre 1 e 13, a uma temperatura de 25 oC. Os parâmetros cinéticos avaliados levaram a concluir que até pH 4 a reação se processa por mecanismo que envolve o a...

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ژورنال

عنوان ژورنال: Journal of the Brazilian Chemical Society

سال: 2007

ISSN: 0103-5053

DOI: 10.1590/s0103-50532007000100019